Product ID:FREON TMC SOLVENT AZEOTROPE
MSDS Date:10/01/1985
FSC:6810
NIIN:00-998-2481
MSDS Number: BGCLR

FREON PRODUCTS DIVISION

CHESTNUT RUN, BLDG 711
WILMINGTON, DE 19898
US

Emergency Phone: 800-441-3637

Info Phone: 302-999-3847/4388

Preparer: T.D.ARMSTRONG, C&P DEPT.

Cage: MO462

FREON PRODUCTS DIVISION

WILMINGTON, DE 19898 US

Telephone: 302-999-3847/4388

Cage: MO462

METHYLENE CHLORIDE (SARA III)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 49.5%

OSHA PEL 500 PPM/C,1000; Z2

ACGIH TLV: 50 PPM, A2; 9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 50.5%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

LD50 LC50 Mixture:5000MG/KG(RAT) FOR CH*2CL*2.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Health Hazards Acute and Chronic:ACUTE:SKIN AND EYE
IRRITATION;HEADACHE,NAUSEA,NARCOSIS. CHRONIC:CNS EFFECTS;WORSEN
ANGINA
Explanation of Carcinogenicity:METHYLENE CHLORIDE IS LISTED CARCINOGEN
BY NTP BASED UPON ANIMAL STUDY.
Effects of Overexposure:LIGHT-HEADEDNESS,GIDDINESS,SHORT OF BREATH,POSS
NARCOSIS,POSS CARDIAC ARRHYTHMIAS AT HIGH CONCENT.
Medical Cond Aggravated by Exposure:SKIN DISORDER,CARDIOVASCULAR
DISEASE.

First Aid:INHAL:REMOVE TO FRESH AIR,CALL DR. DO NOT GIVE EPINEPHRINE OF
SIMILAR DRUGS. SKIN OR EYE CONTACT:FLUSH WITH WATER.

Flash Point:NONE
Extinguishing Media:SML FIRES:DRY CHEMICAL OR CO*2.LG FIRES:FOAM OR
WATER.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA IN AN ENCLOSED
AREA IN FIRES CONDITIONS.
Unusual Fire/Explosion Hazard:DRUM MAY RUPTURE UNDER FIRE CONDITIONS
DECOMPOSITION MAY OCCUR;TOXIC FUMES WHICH ARE IRRITATING.

Spill Release Procedures:VENTILATE AREA-ESPECIALLY LOW AREAS.REMOVE
OPEN FLAMES.USE ABSORBENT TO COLLECT MATERIAL

Handling and Storage Precautions:STORE IN A COOL,DRY,WELL VENTILATED
LOCATION,AWAY FROM ANY AREA WHERE THE FIRE HAZARD MAY BE HIGHLY
SUSCEPTIBLE.WEAR CHEMICAL GOGGLES,RUBBER PROT.GEAR
Other Precautions:WEAR AIRLINE RESPIRATOR.

Respiratory Protection:SELF-CONTAINED BREATHING APPARATUS
Ventilation:AS REQUIRED TO CONTROL MISTS IN AIR
Protective Gloves:RUBBER
Eye Protection:SAFETY GOGGLES
Other Protective Equipment:RUBBER PROTECTIVE CLOTHING.
Supplemental Safety and Health
MIXTURE FORMULA-CCL*3CF*3/CH*2CL*2.ITEM MEETS DEFICNITION FOR TYPE II
UNDER MIL-C-81302.

HCC:T3
Boiling Pt:B.P. Text:97.2F/37C
Vapor Pres:500
Vapor Density:4.9
Spec Gravity:1.42
Evaporation Rate & Reference:0.3 (CCL*4=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR COLORLESS LIQUID,SLIGHT SOLVENT ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS-POWD AL,ZINC,BERYLLIUM ETC
Stability Condition to Avoid:OPEN FLAMES OR HIGH TEMPERATURES
Hazardous Decomposition Products:HYDROCHLORIC & HYDROFLUORIC
ACIDS-POSSIBLE CARBONYL HALIDES

Waste Disposal Methods:KEEP IN COVERED DRUMS PENDING DISPOSAL.PRODUCT
CONTAINS FLUOROCARBON-NOT BIODEGRADABLE.MFR RECOMMENDS RECLAIM BY
DISTILLATION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.